Publications

2024

67. Fantin, M.; Tognella, E.; Antonello, A.; Lorandi, F.; Calore, E.; Macior, A.; Durante, C.; Isse, A. A. Effects of Solvent and Monomer on the Kinetics of Radical Generation in Atom Transfer Radical Polymerization. ChemElectroChem 2024, e202300662., 101313.

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2021

56.  F. Lorandi, T. Liu, M. Fantin, J. Manser, A. Al-Obeidi, M. Zimmerman, K. Matyjaszewski, J.F. Whitacre, Comparative performance of ex situ artificial solid electrolyte interphases for Li metal batteries with liquid electrolytes, iScience, 2021, 24, doi: 10.1016/j.isci.2021.102578.

55.  F. Lorandi, M. Fantin, K. Matyjaszewski, Redox-Initiated RAFT Polymerization and (Electro)chemical Activation of RAFT Agents,  RAFT Polymerization: Methods, Synthesis and Applications: Volume 1 and 22021, pp. 647-677.

2020

54.  G. Szczepaniak, J. Piatkowski, W. Nogas, F. Lorandi, S.S. Yerneni, M. Fantin, A. Ruszczynska, A.E. Enciso, E. Bulska, K. Grela, K. Matyjaszewski, An isocyanide ligand for the rapid quenching and efficient removal of copper residues after Cu/TEMPO-catalyzed aerobic alcohol oxidation and atom transfer radical polymerization, Chemical Science, 2020, 11, 4251-4262, doi: 10.1039/d0sc00623h.

53.  M.R. Martinez, J. Sobieski, F. Lorandi, M. Fantin, S. Dadashi-Silab, G. Xie, M. Olszewski, X. Pan, T.G. Ribelli, K. Matyjaszewski, Understanding the Relationship between Catalytic Activity and Termination in photoATRP: Synthesis of Linear and Bottlebrush Polyacrylates, Macromolecules, 2020, 53, 59-67, doi: 10.1021/acs.macromol.9b02397.

52.  F. Lorandi, M. Fantin, Y. Wang, A.A. Isse, A. Gennaro, K. Matyjaszewski, Atom Transfer Radical Polymerization of Acrylic and Methacrylic Acids: Preparation of Acidic Polymers with Various Architectures, ACS Macro Letters, 2020, 9, 693-699, doi: 10.1021/acsmacrolett.0c00246.

51.  A.E. Enciso, F. Lorandi, A. Mehmood, M. Fantin, G. Szczepaniak, B.G. Janesko, K. Matyjaszewski, p-Substituted Tris(2-pyridylmethyl)amines as Ligands for Highly Active ATRP Catalysts: Facile Synthesis and Characterization, Angewandte Chemie – International Edition, 2020, 59, 14910-14920, doi: 10.1002/anie.202004724.

50.  S. Dadashi-Silab, I.H. Lee, A. Anastasaki, F. Lorandi, B. Narupai, N.D. Dolinski, M.L. Allegrezza, M. Fantin, D. Konkolewicz, C.J. Hawker, K. Matyjaszewski, Investigating Temporal Control in Photoinduced Atom Transfer Radical Polymerization, Macromolecules, 2020, 53, 5280-5288, doi: 10.1021/acs.macromol.0c00888.

 

2019

49.  W. Yan, M. Fantin, N.D. Spencer, K. Matyjaszewski, E.M. Benetti, Translating Surface-Initiated Atom Transfer Radical Polymerization into Technology: The Mechanism of Cu0-Mediated SI-ATRP under Environmental Conditions, ACS Macro Letters, 2019, 8, 865-870, doi: 10.1021/acsmacrolett.9b00388.

48.  W. Yan, M. Fantin, S. Ramakrishna, N.D. Spencer, K. Matyjaszewski, E.M. Benetti, Growing Polymer Brushes from a Variety of Substrates under Ambient Conditions by Cu0-Mediated Surface-Initiated ATRP, ACS Applied Materials and Interfaces, 2019, 11, 27470-27477, doi: 10.1021/acsami.9b09529.

47.  Z. Wang, J. Yan, T. Liu, Q. Wei, S. Li, M. Olszewski, J. Wu, J. Sobieski, M. Fantin, M.R. Bockstaller, K. Matyjaszewski, Control of Dispersity and Grafting Density of Particle Brushes by Variation of ATRP Catalyst Concentration, ACS Macro Letters, 2019, 8, 859-864, doi: 10.1021/acsmacrolett.9b00405.

46.  Z. Wang, F. Lorandi, M. Fantin, Z. Wang, J. Yan, Z. Wang, H. Xia, K. Matyjaszewski, Atom Transfer Radical Polymerization Enabled by Sonochemically Labile Cu-carbonate Species, ACS Macro Letters, 2019, 8, 161-165, doi: 10.1021/acsmacrolett.9b00029.

45.  Z. Wang, M. Fantin, J. Sobieski, Z. Wang, J. Yan, J. Lee, T. Liu, S. Li, M. Olszewski, M.R. Bockstaller, K. Matyjaszewski, Pushing the Limit: Synthesis of SiO2- g-PMMA/PS Particle Brushes via ATRP with Very Low Concentration of Functionalized SiO2-Br Nanoparticles, Macromolecules, 2019, 52, 8713-8723, doi: 10.1021/acs.macromol.9b01973.

44.  Y. Wang, M. Fantin, K. Matyjaszewski, Electrochemically mediated atom transfer radical polymerization with dithiocarbamates as alkyl pseudohalides, Journal of Polymer Science, Part A: Polymer Chemistry, 2019, 57, 376-381, doi: 10.1002/pola.29197.

43.  L. Thevenin, C. Fliedel, M. Fantin, T.G. Ribelli, K. Matyjaszewski, R. Poli, Reductive Termination of Cyanoisopropyl Radicals by Copper(I) Complexes and Proton Donors: Organometallic Intermediates or Coupled Proton-Electron Transfer?, Inorganic Chemistry, 2019, 58, 6445-6457, doi: 10.1021/acs.inorgchem.9b00660.

42.  Y. Sun, S. Lathwal, Y. Wang, L. Fu, M. Olszewski, M. Fantin, A.E. Enciso, G. Szczepaniak, S. Das, K. Matyjaszewski, Preparation of Well-Defined Polymers and DNA-Polymer Bioconjugates via Small-Volume eATRP in the Presence of Air, ACS Macro Letters, 2019, 603-609, doi: 10.1021/acsmacrolett.9b00159.

41.  S. Shanmugam, J. Cuthbert, J. Flum, M. Fantin, C. Boyer, T. Kowalewski, K. Matyjaszewski, Transformation of gels: Via catalyst-free selective RAFT photoactivation, Polymer Chemistry, 2019, 10, 2477-2483, doi: 10.1039/c9py00213h.

40.  T.G. Ribelli, F. Lorandi, M. Fantin, K. Matyjaszewski, Atom Transfer Radical Polymerization: Billion Times More Active Catalysts and New Initiation Systems, Macromolecular Rapid Communications, 2019, 40, doi: 10.1002/marc.201800616.

39.  F. Lorandi, M. Fantin, S. Shanmugam, Y. Wang, A.A. Isse, A. Gennaro, K. Matyjaszewski, Toward Electrochemically Mediated Reversible Addition-Fragmentation Chain-Transfer (eRAFT) Polymerization: Can Propagating Radicals Be Efficiently Electrogenerated from RAFT Agents?, Macromolecules, 2019, 52, 1479-1488, doi: 10.1021/acs.macromol.9b00112.

38.  L. Fu, A. Simakova, S. Park, Y. Wang, M. Fantin, K. Matyjaszewski, Axially ligated mesohemins as bio-mimicking catalysts for atom transfer radical polymerization, Molecules, 2019, 24, doi: 10.3390/molecules24213969.

37.  M. Fantin, F. Lorandi, T.G. Ribelli, G. Szczepaniak, A.E. Enciso, C. Fliedel, L. Thevenin, A.A. Isse, R. Poli, K. Matyjaszewski, Impact of Organometallic Intermediates on Copper-Catalyzed Atom Transfer Radical Polymerization, Macromolecules, 2019, 52, 4079-4090, doi: 10.1021/acs.macromol.9b00870.

36.  C. Fang, M. Fantin, X. Pan, K. De Fiebre, M.L. Coote, K. Matyjaszewski, P. Liu, Mechanistically Guided Predictive Models for Ligand and Initiator Effects in Copper-Catalyzed Atom Transfer Radical Polymerization (Cu-ATRP), Journal of the American Chemical Society, 2019, 141, 7486-7497, doi: 10.1021/jacs.9b02158.

35.  S. Dadashi-Silab, F. Lorandi, M. Fantin, K. Matyjaszewski, Redox-switchable atom transfer radical polymerization, Chemical Communications, 2019, 55, 612-615, doi: 10.1039/C8CC09209E.

2018

34.  G. Xie, M.R. Martinez, W.F.M. Daniel, A.N. Keith, T.G. Ribelli, M. Fantin, S.S. Sheiko, K. Matyjaszewski, Benefits of Catalyzed Radical Termination: High-Yield Synthesis of Polyacrylate Molecular Bottlebrushes without Gelation, Macromolecules, 2018, 51, 6218-6225, doi: 10.1021/acs.macromol.8b00849.

33.  Y. Wang, M. Fantin, K. Matyjaszewski, Synergy between Electrochemical ATRP and RAFT for Polymerization at Low Copper Loading, Macromolecular Rapid Communications, 2018, 39, doi: 10.1002/marc.201800221.

32.  T.G. Ribelli, M. Fantin, J.C. Daran, K.F. Augustine, R. Poli, K. Matyjaszewski, Synthesis and Characterization of the Most Active Copper ATRP Catalyst Based on Tris[(4-dimethylaminopyridyl)methyl]amine, Journal of the American Chemical Society, 2018, 140, 1525-1534, doi: 10.1021/jacs.7b12180.

31.  X. Pan, M. Fantin, F. Yuan, K. Matyjaszewski, Externally controlled atom transfer radical polymerization, Chemical Society Reviews, 2018, 47, 5457-5490, doi: 10.1039/c8cs00259b.

30.  F. Lorandi, Y. Wang, M. Fantin, K. Matyjaszewski, Ab Initio Emulsion Atom-Transfer Radical Polymerization, Angewandte Chemie – International Edition, 2018, 57, 8270-8274, doi: 10.1002/anie.201804647.

29.  F. Lorandi, M. Fantin, A.A. Isse, A. Gennaro, K. Matyjaszewski, New protocol to determine the equilibrium constant of atom transfer radical polymerization, Electrochimica Acta, 2018, 260, 648-655, doi: 10.1016/j.electacta.2017.12.011.

28.  F. Lorandi, M. Fantin, A.A. Isse, A. Gennaro, Electrochemical triggering and control of atom transfer radical polymerization, Current Opinion in Electrochemistry, 2018, 8, 1-7, doi: 10.1016/j.coelec.2017.11.004.

27.  F. Lorandi, M. Fantin, F. De Bon, A.A. Isse, A. Gennaro, Electrochemical procedures to determine thermodynamic and kinetic parameters of atom transfer radical polymerization,  ACS Symposium Series, 2018, pp. 161-189.

26.  L. Fu, A. Simakova, M. Fantin, Y. Wang, K. Matyjaszewski, Direct ATRP of Methacrylic Acid with Iron-Porphyrin Based Catalysts, ACS Macro Letters, 2018, 7, 26-30, doi: 10.1021/acsmacrolett.7b00909.

25.  M. Fantin, S.N. Ramakrishna, J. Yan, W. Yan, M. Divandari, N.D. Spencer, K. Matyjaszewski, E.M. Benetti, The Role of Cu0 in Surface-Initiated Atom Transfer Radical Polymerization: Tuning Catalyst Dissolution for Tailoring Polymer Interfaces, Macromolecules, 2018, 51, 6825-6835, doi: 10.1021/acs.macromol.8b01306.

24.  D.R. D’Hooge, M. Fantin, A.J.D. Magenau, D. Konkolewicz, K. Matyjaszewski, Two-compartment kinetic Monte Carlo modelling of electrochemically mediated ATRP, Reaction Chemistry and Engineering, 2018, 3, 866-874, doi: 10.1039/c8re00156a.

23.  F. De Bon, M. Fantin, A.A. Isse, A. Gennaro, Electrochemically mediated ATRP in ionic liquids: Controlled polymerization of methyl acrylate in [BMIm][OTf], Polymer Chemistry, 2018, 9, 646-655, doi: 10.1039/c7py02134h.

2017

22.  Z. Wang, X. Pan, L. Li, M. Fantin, J. Yan, Z. Wang, Z. Wang, H. Xia, K. Matyjaszewski, Enhancing Mechanically Induced ATRP by Promoting Interfacial Electron Transfer from Piezoelectric Nanoparticles to Cu Catalysts, Macromolecules, 2017, 50, 7940-7948, doi: 10.1021/acs.macromol.7b01597.

21.  Y. Wang, F. Lorandi, M. Fantin, P. Chmielarz, A.A. Isse, A. Gennaro, K. Matyjaszewski, Miniemulsion ARGET ATRP via Interfacial and Ion-Pair Catalysis: From ppm to ppb of Residual Copper, Macromolecules, 2017, 50, 8417-8425, doi: 10.1021/acs.macromol.7b01730.

20.  Y. Wang, M. Fantin, S. Park, E. Gottlieb, L. Fu, K. Matyjaszewski, Electrochemically Mediated Reversible Addition-Fragmentation Chain-Transfer Polymerization, Macromolecules, 2017, 50, 7872-7879, doi: 10.1021/acs.macromol.7b02005.

19.  T.G. Ribelli, K.F. Augustine, M. Fantin, P. Krys, R. Poli, K. Matyjaszewski, Disproportionation or Combination? the Termination of Acrylate Radicals in ATRP, Macromolecules, 2017, 50, 7920-7929, doi: 10.1021/acs.macromol.7b01552.

18.  F. Lorandi, F. De Bon, M. Fantin, A.A. Isse, A. Gennaro, Electrochemical characterization of common catalysts and initiators for atom transfer radical polymerization in [BMIm][OTf], Electrochemistry Communications, 2017, 77, 116-119, doi: 10.1016/j.elecom.2017.03.003.

17.  H.C. Lee, M. Fantin, M. Antonietti, K. Matyjaszewski, B.V.K.J. Schmidt, Synergic Effect between Nucleophilic Monomers and Cu(II) Metal-Organic Framework for Visible-Light-Triggered Controlled Photopolymerization, Chemistry of Materials, 2017, 29, 9445-9455, doi: 10.1021/acs.chemmater.7b03541.

16.  P. Krys, M. Fantin, P.V. Mendonça, C.M.R. Abreu, T. Guliashvili, J. Rosa, L.O. Santos, A.C. Serra, K. Matyjaszewski, J.F.J. Coelho, Mechanism of supplemental activator and reducing agent atom transfer radical polymerization mediated by inorganic sulfites: Experimental measurements and kinetic simulations, Polymer Chemistry, 2017, 8, 6506-6519, doi: 10.1039/c7py01319a.

15.  M. Fantin, F. Lorandi, A. Gennaro, A.A. Isse, K. Matyjaszewski, Electron Transfer Reactions in Atom Transfer Radical Polymerization, Synthesis (Germany), 2017, 49, 3311-3322, doi: 10.1055/s-0036-1588873.

14.  M. Fantin, A.A. Isse, K. Matyjaszewski, A. Gennaro, ATRP in Water: Kinetic Analysis of Active and Super-Active Catalysts for Enhanced Polymerization Control, Macromolecules, 2017, 50, 2696-2705, doi: 10.1021/acs.macromol.7b00246.

13.  M. Fantin, P. Chmielarz, Y. Wang, F. Lorandi, A.A. Isse, A. Gennaro, K. Matyjaszewski, Harnessing the Interaction between Surfactant and Hydrophilic Catalyst To Control eATRP in Miniemulsion, Macromolecules, 2017, 50, 3726-3732, doi: 10.1021/acs.macromol.7b00530.

12.  P. Chmielarz, M. Fantin, S. Park, A.A. Isse, A. Gennaro, A.J.D. Magenau, A. Sobkowiak, K. Matyjaszewski, Electrochemically mediated atom transfer radical polymerization (eATRP), Progress in Polymer Science, 2017, 69, 47-78, doi: 10.1016/j.progpolymsci.2017.02.005.

11.  K.F. Augustine, T.G. Ribelli, M. Fantin, P. Krys, Y. Cong, K. Matyjaszewski, Activation of alkyl halides at the Cu0 surface in SARA ATRP: An assessment of reaction order and surface mechanisms, Journal of Polymer Science, Part A: Polymer Chemistry, 2017, 55, 3048-3057, doi: 10.1002/pola.28585.

2016

10.  X. Pan, C. Fang, M. Fantin, N. Malhotra, W.Y. So, L.A. Peteanu, A.A. Isse, A. Gennaro, P. Liu, K. Matyjaszewski, Mechanism of Photoinduced Metal-Free Atom Transfer Radical Polymerization: Experimental and Computational Studies, Journal of the American Chemical Society, 2016, 138, 2411-2425, doi: 10.1021/jacs.5b13455.

9.      F. Lorandi, M. Fantin, A.A. Isse, A. Gennaro, Electrochemically mediated atom transfer radical polymerization of: N -butyl acrylate on non-platinum cathodes, Polymer Chemistry, 2016, 7, 5357-5365, doi: 10.1039/c6py01032f.

8.      S. Lanzalaco, M. Fantin, O. Scialdone, A. Galia, A.A. Isse, A. Gennaro, K. Matyjaszewski, Atom transfer radical polymerization with different halides (F, Cl, Br, and I): Is the process “living” in the presence of fluorinated initiators?, Macromolecules, 2016, 50, 192-202, doi: 10.1021/acs.macromol.6b02286.

7.      M. Fantin, S. Park, Y. Wang, K. Matyjaszewski, Electrochemical Atom Transfer Radical Polymerization in Miniemulsion with a Dual Catalytic System, Macromolecules, 2016, 49, 8838-8847, doi: 10.1021/acs.macromol.6b02037.

6.      M. Fantin, F. Lorandi, A.A. Isse, A. Gennaro, Sustainable Electrochemically-Mediated Atom Transfer Radical Polymerization with Inexpensive Non-Platinum Electrodes, Macromolecular rapid communications, 2016, 37, 1318-1322, doi: 10.1002/marc.201600237.

5.      M. Fantin, A.A. Isse, A. Venzo, A. Gennaro, K. Matyjaszewski, Atom Transfer Radical Polymerization of Methacrylic Acid: A Won Challenge, Journal of the American Chemical Society, 2016, 138, 7216-7219, doi: 10.1021/jacs.6b01935.

4.      M. Fantin, A.A. Isse, N. Bortolamei, K. Matyjaszewski, A. Gennaro, Electrochemical approaches to the determination of rate constants for the activation step in atom transfer radical polymerization, Electrochimica Acta, 2016, 222, 393-401, doi: 10.1016/j.electacta.2016.10.191.

2015

3.      F. Lorandi, M. Fantin, A.A. Isse, A. Gennaro, RDRP in the presence of Cu0: The fate of Cu(I) proves the inconsistency of SET-LRP mechanism, Polymer, 2015, 72, 238-245, doi: 10.1016/j.polymer.2015.04.007.

2.      M. Fantin, A.A. Isse, A. Gennaro, K. Matyjaszewski, Understanding the Fundamentals of Aqueous ATRP and Defining Conditions for Better Control, Macromolecules, 2015, 48, 6862-6875, doi: 10.1021/acs.macromol.5b01454.

2014

1.      D. Konkolewicz, P. Krys, J.R. Góis, P.V. Mendonça, M. Zhong, Y. Wang, A. Gennaro, A.A. Isse, M. Fantin, K. Matyjaszewski, Aqueous RDRP in the presence of Cu0: The exceptional activity of CuI confirms the SARA ATRP mechanism, Macromolecules, 2014, 47, 560-570, doi: 10.1021/ma4022983.